To start my own best-of collection, the first application that comes to my mind is Ant Movie Catalog. While apparently not part of the Sourceforge listing, it's an good example of freeware that outperform by far any payware I know of.
It evolved to cover now every important aspects of a good media database: Easy and complete interface, powerful import/export functionality, powerfull scripts (constently updated but you can create yours) that allow you to grab the DVD cover and information from various specialised web sites, loan management (very important!), and last but not least,a highly configurable print-out interface.
Also, have a look at the other less popular software from the same author.